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|Section2= |Section3= }} Dirhenium decacarbonyl is the inorganic compound with the chemical formula Re2(CO)10 . Commercially available, it is used as a starting point for the synthesis of many rhenium carbonyl complexes. It was first reported in 1941 by Walter Hieber, who prepared it by reductive carbonylation of rhenium. The compound consists of a pair of square pyramidal Re(CO)5 units joined via a Re-Re bond, which produces a homoleptic carbonyl complex. ==History== In the 1930s Robert Mond developed methods which used increased pressure and temperature to produce various forms of metal carbonyl . A prominent scientist of the twentieth century, Walter Hieber was crucial to the further development of specifically the dirhenium decacarbonyl. Initial efforts produced mononuclear metal complexes, but upon further evaluation, Hieber discovered that by using Re2O7 as a starting material with no solvent, a dirhenium complex could be achieved producing a Re-Re interaction. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Dirhenium decacarbonyl」の詳細全文を読む スポンサード リンク
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